Constants | Periodic Table The following reaction was monitored as a function of
ID: 1081883 • Letter: C
Question
Constants | Periodic Table
The following reaction was monitored as a function of time:
AB+C
A plot of ln[A] versus time yields a straight line with slope 5.0×103 /s .
Part A
Part complete
What is the value of the rate constant (k) for this reaction at this temperature?
Express your answer using two significant figures.
5.0×103
Previous Answers
Correct
Part B
Part complete
Write the rate law for the reaction.
Previous Answers
Correct
Part C
Part complete
What is the half-life?
Express your answer using two significant figures.
140
Previous Answers
Correct
Part D
If the initial concentration of A is 0.220 M , what is the concentration after 235 s ?
Request Answer
Constants | Periodic Table
The following reaction was monitored as a function of time:
AB+C
A plot of ln[A] versus time yields a straight line with slope 5.0×103 /s .
Part A
Part complete
What is the value of the rate constant (k) for this reaction at this temperature?
Express your answer using two significant figures.
k =5.0×103
s1Explanation / Answer
1. As the slope is given,The slope is the rate constant of the reaction.
Determining the units of rate constants can give us the order
Rate Concentration
Also the first order equation,
ln[A]=-kt + ln[Ao]
Hence,this is a first order reaction
As rate constant of 1st order is per second
rate constant (k)= 0.0050
2. Rate law= Rate=k[A]
3. Half life = ln2/rate constant= 40 seconds
4. Initial conc.= 0.220 Final be=x Time=235second,k=0.005
ln[A]=-kt + ln[Ao]
ln[Ao/A]=kt
ln[0.22/A]= 0.005*235
ln[0.22/A]=1.175
Taking anti log'
0.22/A=3.23
A=0.067
Final conc.= 0.067