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I have made one attempt at arranging the paths and got it wrong. I don\' kno w i

ID: 1323715 • Letter: I

Question

I have made one attempt at arranging the paths and got it wrong. I don' kno w if I got all or just some of them wrong. I do however know that the value I found for Ca+ is correct.

Thanks in advance.

Elements that appear in the same column of the periodic table often share similar chemical properties. In the case of the alkaline earth metals, this is troublesome since the body treats calcium (necessary for proper bone growth) and radium (a radioactive element) as chemically similar, storing both in bone marrow. The radium then bombards nearby bone cells with alpha particles, causing them to crumble. Radium poisoning investigations often center on the identification of radium and its isotopes in bone samples using a mass spectrometer. Pictured is a schematic of a simplified mass spectrometer, showing the paths of different calcium, barium (another alkaline earth metal) and radium isotopes entering the chamber. The region shown is immersed in a constant magnetic field of 0.552 T pointing out of the plane of the schematic. Motion of the positively- charged isotopes toward the right was initiated by a potential difference of 2773 V on the two plates shown. The isotopes start from rest at the positively-charged plate. Using the data shown in the table below, calculate the path radius of the Ca+ ion. Number 0.086595 m radius of the Ca+ ion. Using the same data table, match the particles to their path label. I have made one attempt at arranging the paths and got it wrong. I don' kno w if I got all or just some of them wrong. I do however know that the value I found for Ca+ is correct. Thanks in advance.

Explanation / Answer

r = (m/qB) sqrt(2eV/m)

radius is directly proportioaal to ratio of m/q


so large m/q corresponds to large radius

so

for Ca+ :   m/q    = 0.666e-25/1.6e-19 = 0.416 um

for Ca2+: m/q = 0.666 e-25/3.204 e-19 = 0.207 um

for Ba+ : m/q = 2.28 e-25/1.603 e-19 = 1.422 um

for Ba2+, m/q = 2.28 e-25/3.204 e-19 = 0.711 um

for Ra+ , m/q = 3.75 e-25 /1.603 e-19 = 2.33 um

for Ra2+, m/q = 3.75 e-25/(3.204e-19) =1.17 um

for Ra3+. m/q = 3.75 e-25/4.806 e-19 = 0.78um

so


correct matching will be

path A   is Ca2+

path B is Ca+

path C is Ba2+

path D is Ra3+

path E is Ra2+

path F is Ba+

path G is Ra+