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Consider the titration of 25.0 mL of 0.150 M HBr with 0.0750 M NaOH. What is the

ID: 489206 • Letter: C

Question

Consider the titration of 25.0 mL of 0.150 M HBr with 0.0750 M NaOH. What is the volume of NaOH required to reach the equivalence point? (a) 25.0 mL (b) 50.0 mL (c) 12.5 mL

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What two assumptions must be true for the pH of an intermediate of a diprotic acid to equal (pKa1 + pKa2)/2? Overall 70 57 (a) Ka2F >> Kw and Ka1F << F (b) Ka2F << Kw and Ka1F << F (c) Ka1F >> Kw and Ka2F << F

Explanation / Answer

Q.1) Consider the titration of 25.0 mL of 0.150 M HBr with 0.0750 M NaOH. What is the volume of NaOH required to reach the equivalence point?

Answer :

At equivalence, # of milimoles of monoprotic acid = # of milimoles of monoacidic base.

# of milimoles = Molarity x Volume (in mL)

# of milimoles of HBr = 0.150 x 25.0

Let Volume of NaOh required = V mL

and # of milimoles of NaOH = 0.0750 x V

Hence we write,

0.0750 x V = 0.150 x 25.0

V = 0.150 x 25.0 / 0.075

V = 50.00 mL.

50.00 mL of 0.075 M NaOH will be required at equivalence.

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