Classify the following reactions as oxidative addition, reductive elimination, m

Question

Classify the following reactions as oxidative addition, reductive elimination, migratory insertion, elimination, -hydride elimination, ligand substitution, ligand dissociation, ligand addition, oxidative coupling, etc. There may be more than one step and that the equations are not necessarily balanced or completely list all possible products. If there is more than one step to label, make sure you list the steps in the correct order if the order is important. NO discussion or justification is necessary.

s/PS2- 2017.pdf l. (9 points) Classify the following reactions as oxidative addition, reductive elimination, migratory insertion, elimination, B-hydride elimination, ligand substitution, ligand dissociation, ligand addition, oxidative coupling, etc. There may be more than one step and that the equations are not necessarily balanced or completely list all possible products. If there is more than one step to label, make sure you list the steps in the correct order if the order is important. No discussion or justification is necessary a) Mn(SiMe3)(dppe) H303 H2 SiMe Me Si ocu Re co PMe3 OC I CO OC PMe CO CO c) Cp2Zr(PMe3)2 H2 Me t PMe3 d) Rh(CH2CH2CH2CH300dimpe)(pMe CH2-CH-CH2CH pa

Explanation / Answer

Answers 1.

For Reaction A - Ligand Substitution Reaction.

For Reaction B - Oxidative Addition

For Reaction C - Ligand Dissociation

For Reaction D - Ligand Dissociation

For Reaction E - Ligand Addition

For Reaction F - Migratory Insertation.

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