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Please help!!! I know NH4OCONH2 is a solid so we don\'t count it when looking fo

ID: 539733 • Letter: P

Question

Please help!!! I know NH4OCONH2 is a solid so we don't count it when looking for equilibrium and I have already tried making 2 separate ice tables and I just can't seem to figure out what method to use (quadratic formula or approximation) and no matter what I try I keep getting insane numbers. Thank you!

At a certain temperature, Kp = 2.9 times 10^-5 for the following reaction: NH_4 OCONH_2 (s) 2 NH_3 (g) + CO_2 (g) In an experiment carried out at this temperature, a certain amount of NH_4 OCONH_2 and 0.500 atm of CO_2 is placed in a container and allowed to come to equilibrium. Calculate the partial pressures of all gases at equilibrium.

Explanation / Answer

NH4OCONH2 (s)   ----------------> 2 NH3 (g) + CO2 (g)

          -                                              0                  0.500 atm

         - x                                             2x                0.5 + x

Kp = P2NH3 x PCO2

2.9 x 10^-5 = (2x)^2 x (0.5 + x)

2.9 x 10^-5 = 4x^2 (0.5 + x)

2.9 x 10^-5 = 2 x^2 + 4x^3

4x^3 + 2x^2 - 2.9 x 10^-5 = 0

x = 3.79 x 10^-3

partial pressure of all gases :

PNH3 = 0.00758 atm

PCO2 = 0.504 atm