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Part S ACID BASE TITRATION (neutralization experiment): (for this experiment,I d

ID: 573528 • Letter: P

Question

Part S ACID BASE TITRATION (neutralization experiment): (for this experiment,I drop-0.05 mL) 17. Get a dropper of unknown molarity HNO, and a dropper of 0.10 M NaOH. Add 10 drops of acid to the beaker and add a few drops of universal indicator. Now add drops of 0.10 M NaOH until the acid is neutralized. USE THIS FORMULA #11 x M.ius v, "apoi 1 x M.-x v.." a) How many ml. of base were needed to neutralize the 10 drops of acid? b) Calculate the molarity of the HNO c) Practice: If 25 mL of 0.10 M NaOH neutralize 15 mL of H,SO, what is the molarity of the H,SO.? ze l 5 mL of HNO, what is the molanty oftheHNO.. d) Practice: If 15 mL of 0.10 M e) Practice: If 1S ml. of 0, 10 M NaOH neutralize 25 ml. of HCI, what is the molarity of the HC1? Solution ,5mlO 2. Part 6-COLLIGAT e for homework . Look at the results in the data table below and answer question W2 below 6 min 140 man Time required to Boil Time required to Freeze 5 unin 120 min mmin 160 min

Explanation / Answer

Ans. #17.b Given-

            Volume of NaOH solution consumed = 0.8 mL

            Molarity of NaOH solution = 0.10 M

            Volume of HNO3 solution taken = 10 drops

= 10 drops x (0.05 mL/ drop) = 0.50 mL

# Method 1: Balanced reaction:    HNO3(aq) +NaOH(aq) -------> NaNO3(aq) + H2O(l)

According to the stoichiometry of balanced reaction, 1 molHNO3 is neutralized by 1 mol NaOH.

So, at equivalence point, the moles of NaOH consumed must be equal to the moles of HNO3 taken.

Now,

Moles of NaOH consumed = Molarity of NaOH x Volume of NaOH solution in liters

                                                = 0.10 M x 0.8 mL                                        ; [1 mL = 0.001 L]

                                                = (0.10 mol/ L) x 0.0008 L                           ; [1 M = 1 mol/ L]

                                                = 0.00008 mol

So, moles of HNO3 taken = Moles of NaOH consumed = 0.00008 mol

# Volume of HNO3 solution taken = 0.50 mL = 0.0005 L

Now,

            Molarity of HNO3 = Moles of HNO3 / Volume of HNO3 solution in liters

                                                = 0.00008 mol / 0.0005 L

                                                = 0.16 mol/ L

                                                = 0.16 M

# Method 2: At equivalence point-

                        A x (M1V1), acid = B x (M2V2), base

            Where, A = number of H+ given by acid

                        B = number of OH- given by base

                        M = Molarity of respective solutions

                        V = Volume of respective solution

Here, both the acid and bases are monoprotic and monobasic. So, the values of A=B=1.

Given-

            Volume of NaOH solution consumed = 0.8 mL

            Molarity of NaOH solution = 0.10 M

            Volume of HNO3 solution taken = 10 drops

= 10 drops x (0.05 mL/ drop) = 0.50 mL

Putting the values in above equation-

            1 x (M1 x 0.50 mL) = 1 x (0.10 M x 0.80 mL)

            Or, M1 = (0.10 M x 0.80 mL) / 0.50 mL

            Hence, M1 = 0.16 M

Therefore, Molarity of HNO3 = 0.16 M