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Fill in the appropriate term for each of thedefinitions below: a) An S N type re

ID: 687406 • Letter: F

Question

Fill in the appropriate term for each of thedefinitions below:
a) An SN type reaction where solvent is the nucleophile- __________________ b) Interference by large groups, which slowsdown the rate of a reaction - _____________ c) An energy maximum that lies betweenreactants and products on the reaction coordinate -_______ d) A reaction that could potentially give twoconstitutional isomers but gives only one - _________ e) Term used when a reactive agent is generatedin the presence of the substrate - ______________ f) Interference by large groups which slowsdown the rate of a reaction - ___________ g) Addition of groups to the same side of adouble bond - ________________ h) An energy minimum that lies betweenreactants and products on the reaction coordinate -________ i) Stereochemical outcome of a reaction thatproceeds through a carbocation - ____________ j) Orientation of groups lost in anE2 elimination - ____________ Fill in the appropriate term for each of thedefinitions below:
a) An SN type reaction where solvent is the nucleophile- __________________ b) Interference by large groups, which slowsdown the rate of a reaction - _____________ c) An energy maximum that lies betweenreactants and products on the reaction coordinate -_______ d) A reaction that could potentially give twoconstitutional isomers but gives only one - _________ e) Term used when a reactive agent is generatedin the presence of the substrate - ______________ f) Interference by large groups which slowsdown the rate of a reaction - ___________ g) Addition of groups to the same side of adouble bond - ________________ h) An energy minimum that lies betweenreactants and products on the reaction coordinate -________ i) Stereochemical outcome of a reaction thatproceeds through a carbocation - ____________ j) Orientation of groups lost in anE2 elimination - ____________

Explanation / Answer

a) Solvolysis with Sn1 b) Steric hindrance c) Energy of Activation d) Stereospecific f) Steric hindrance g) Syn addition i) Racemic mixture j) Anti orientation