Please help Using the Equilibrium Constant Part A The reversible chemical reacti
ID: 696022 • Letter: P
Question
Please help
Using the Equilibrium Constant Part A The reversible chemical reaction nitially, only A and B are present, each at 2.00 M. What is the final concentration of A once equilibrium is reached? has the following equilibrium constant: Express the molar concentration numerically using two significant figures CID = 6.9 Hints A-0.55 M Submit Kc My Answers Give Up Correct Part B What is the final concentration of D at equilibnum if the initial concentrations are [A] = 1.00 M and [B] = 2.00 M ? Express the molar concentration numerically using two significant figures Hints AS D-3.7 Submit My Answers Give Up Incorrect; Try Again; 4 attempts remainingExplanation / Answer
Let's prepare the ICE table
[A] [B] [C] [D]
initial 1.0 2.0 0 0
change -1x -1x +1x +1x
equilibrium 1.0-1x 2.0-1x +1x +1x
Equilibrium constant expression is
Kc = [C]*[D]/[A]*[B]
6.9 = (1*x)(1*x)/((1-1*x)(2-1*x))
6.9 = (1*x^2)/(2-3*x + 1*x^2)
13.8-20.7*x + 6.9*x^2 = 1*x^2
13.8-20.7*x + 5.9*x^2 = 0
Let's solve this quadratic equation
Comparing it with general form: (ax^2+bx+c=0)
a = 5.9
b = -20.7
c = 13.8
solution of quadratic equation is found by below formula
x = {-b + (b^2-4*a*c)}/2a
x = {-b - (b^2-4*a*c)}/2a
b^2-4*a*c = 1.028*10^2
putting value of d, solution can be written as:
x = {20.7 + (1.028*10^2)}/11.8
x = {20.7 - (1.028*10^2)}/11.8
solutions are :
x = 2.614 and x = 0.895
x can't be 2.614 as this will make the concentration negative.so,
x = 0.895
At equilibrium:
[D] = +1x = 0.895 M
Answer: 0.90 M