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If ?G o is positive (it should be), why does some of the borax still dissolve at

ID: 775087 • Letter: I

Question

If ?Go is positive (it should be), why does some of the borax still dissolve at room temperature? (Hint: what is the difference between ?G and ?Go?)

Any help would be appreciated. I would like to understand the concept rather than be fed an answer as well please.

We did a lab for the dissolution of Borax. The dissolution is endothermic and the Ksp increased with temperature. Delta G^0 was positive at all temperatures, though as temperature increased, Delta G^0 decreased. If ?Go is positive (it should be), why does some of the borax still dissolve at room temperature? (Hint: what is the difference between ?G and ?Go?)

Explanation / Answer

DeltaG0 = - RT ln K

If DeltaG0 is positive, K will be less than one, but if it is not too large a positive number compare it with RT, then K can still be large enough for us to say that the reaction does go to some noticeable extent.