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Can someone please help me solve the attached problems, thanks. The strain energ

ID: 791225 • Letter: C

Question

Can someone please help me solve the attached problems, thanks.

The strain energy (kcal/mole) of a single CH3:R gauche interaction (where R represents a generic alkyl group) for the following compound is_kcal/mole. Please enter the numerical value, rounded to two decimal places and without units, into the Blackboard answer. H H Total Strain Energy is equal to 5.84 kcal/mole Assemble a model of the compound below in the conformation shown. What is the correct position or me amine substituent? Which of the following statements is correct? F F Compound P Compound 0 Compound P is a stronger acid than compound Q. Compound P is a weaker acid than compound Q. Compound P and compound Q have equal strength as acids.

Explanation / Answer

14) 5.84 /2

2.92 answer <--------

15)

X = NH2

rest all positions =fill with H atoms

16)Your answers : compound P is weaker than Q

With increase in atomic size from F to I ,bond length of H----X
bond increases and so bond dissociation energy decreases.
Hence,ionisation of H---X increases,therefore acidic strength
increases in the order
HF < HCl < HBr < HI