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Partial structure of ciguatera toxin in shown above. The first steps in characte

ID: 851499 • Letter: P

Question

Partial structure of ciguatera toxin in shown above. The first steps in characterizing new substances typically involve determining physical properties. In a freezing point experiment, a 126 mg sample of pure ciguatera toxin was dissolved in 5.00 g of carbon tetrachloride (which has a freezing point = -23.0 degree C and a freezing point depression constant = 30.0) and the freezing point of the solution was observed to be -23.69 degree C. From this experiment, calculate the molar mass of ciguatera toxin.

Explanation / Answer


DTf = Kf*m

DTf = Tf0-Tf
= -23-(-23.69) = 0.69
Kf= 30 C/mol
m= molality = 0.69/30 = 0.023 molal
0.023 = 0.126/Mw*1000/5
Mw of ciguatera = 0.126/0.023*1000/5
= 1095.65 g/mol