Predict the product of the reaction of prong with each of the following: (a) Lit

Question

Predict the product of the reaction of prong with each of the following: (a) Lithium aluminum hydride, followed by water (b) Sodium borohydride, methanol (c)Hydrogen (nickel catalyst) (d) Methylmagnesium iodide, followed by dilute acid (e)Sodium acetylide, followed by dilute acid (f) Phenyllithium, followed by dilute acid (g) Methanol containing dissolved hydrogen chloride (h)Ethylene glycol, p-toluenesulfonic acid, benzene (i) Aniline (C6H5NH2) (j)Dimethylamine, p-toluenesulfonic acid, benzene (k) Hydroxylamine (l) Hydrazine (m)Product of part (1) heated in triethylene glycol with sodium hydroxide (n) p-Nitrophenylhydrazine (o) Semicarbazide (p) Ethylidenetriphenylphosphorane (q)Sodium cyanide with addition of sulfuric acid (r)Chromic acid

Explanation / Answer

a)CH3CH2CHO + LiAlH4/H2O ------------>CH3CH2CH2OH (1-Propanol)

b)CH3CH2CHO + NaBH4/H2O2 ------------> CH3CH2CH2OH (1-Propanol)

c) CH3CH2CHO + H2/Ni ------------> CH3CH2CH2OH

d) CH3CH2CHO + i)CH3MgI/ii)H2O ------------> CH3CH2CH(OH)CH3

e) 1-pentyn-3ol

f) phenyl propanol

g)propanal dimethyl acetal

h) 2 ethyl 1,3 dioxolane

i)N-propylideneaniline

j)1-(dimethyl amino)-propene

k) propanal oxime

l) propane hydrazone

m) propane

n) propanal paranitrophenyl hydrazone

o)propanal semicarbazone

p) 2-pentene

q) propanal cynohydrin

r) propanoic acid

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