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Show and explain all work. The absorption spectra of solutions containing Br2 ar

ID: 898952 • Letter: S

Question

Show and explain all work.

The absorption spectra of solutions containing Br2 are solvent-dependent. When elemental bromine is dissolved in nonpolar solvents such as hexane, a single absorption band in the visible spectrum is observed near 500 nm. When Br2 is dissolved in methanol, however, this absorption band shifts and a new band is formed. Account for the appearance of the new band. Is the 500 nm band likely to shift to a longer or shorter wavelength in methanol? Why? In your answers, you should show clearly how appropriate orbitals of Br2 and methanol interact.

Explanation / Answer

Show and explain all work. The absorption spectra of solutions containing Br2 ar