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Preparing a Buffer Calculate the number of grams of ammonium chloride that must

ID: 943541 • Letter: P

Question

Preparing a Buffer

Calculate the number of grams of ammonium chloride that must be added to 2.00 L of a 0.500 M ammonia solution to obtain a buffer of pH = 9.20. Assume the volume of the solution does not change as the solid is added. Kb for ammonia is 1.80×105.

Calculate the number of grams of ammonium chloride that must be added to 2.00  of a 0.500  ammonia solution to obtain a buffer of pH = 9.20. Assume the volume of the solution does not change as the solid is added.  for ammonia is .

60.7 g 30.4 g 1.52 g 0.568 g 1.59×105 g

Explanation / Answer

pOH = pKb + log(conjugate/base)

pKb = -logKb= 4.74

V = 2 L

M = 0.4

pOH = 14-pH = 4.8

pOH = pKb + log(conjugate/base)

4.8 = 4.74 + log(conjugate/0.5)

conjugate = (10^(4.8-4.74)) * 0.5

copnjugate = 0.574 M

mol = MV = 0.574*2 = 1.148 mol fo NH4Cl

mass = mol*MW = 1.148*53.491 = 61.407668 g of NH4Cl

nearest answe is 60.7 g