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After the desired amide has been purified, the question is: Is it really the ami

ID: 962153 • Letter: A

Question

After the desired amide has been purified, the question is: Is it really the amide? And how pure is it? • Which method can be used to answer this? IR is very useful in this case. • Why is IR so useful in this case? Carbonyl peaks for the amide, acid chloride and carboxylic acid are easily differentiated. Look up the IR absorptions for these different functionalities. • After an IR spectrum is recorded, analyze it carefully and determine whether the product is pure.

QUESTION:

The three carbonyl compounds in this reaction sequence are easily distinguished by IR spectroscopy because:

Question 6 options:

The substitution of the aromatic ring is different.

They have different fingerprint regions

Some are solids, some are liquids and this will be apparent when preparing a sample for IR analysis.

Each has its C=O strech absorption in a distinctly different region.

The acid has a big OH absorption.

The substitution of the aromatic ring is different.

They have different fingerprint regions

Some are solids, some are liquids and this will be apparent when preparing a sample for IR analysis.

Each has its C=O strech absorption in a distinctly different region.

The acid has a big OH absorption.

Explanation / Answer

Each has its C=O strech absorption in a distinctly different region.

A sharp absorption peak for amides, C=O at 1700-1630 cm^-1