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Please help, I only need help on part (c). I cannot figure out how to reach that

ID: 975905 • Letter: P

Question

Please help, I only need help on part (c). I cannot figure out how to reach that answer. Everything else has been answered.

The following data were obtained when a Ca2+ ion-selective electrode was immersed standard solutions whose ionic strength was constant at 2.0 M.

(a) Prepare a calibration curve and find the least-squares slope and intercept.



(b) Calculate the value of in the equation below.
NOTE: convert the slope from part (a) to Volts.
0.951 (3 decimal places)


(c) For a measured potential, the calibration curve gives us log[Ca2+]. We can compute [Ca2+] = 10log[Ca2+]. Calculate [Ca2+] of a sample that gave a reading of 26.9 mV in four replicate measurements.

slope 28.14 (mV, 2 decimal places) intercept 51.10 (2 decimal places)

Explanation / Answer

A plot of log (Ca+2) Vs E (mV) is shown below

the slope is 28.14 and intercept is 51.09

slope = 28.14*10-3V

Slope =(0.05916/2)*B= 28.14*10-3

B = 28.14*10-3*2/0.05916

B= 0.9513

c) given E= -26.9 mV

-26.9= 51.09 +28.14 log (Ca+2)

-77.99 = 28.14 log (Ca+2)

Ca+2= 0.062568