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Consider two cells, the first with Al and Ag electrodes, and the second with Zn

ID: 991537 • Letter: C

Question

Consider two cells, the first with Al and Ag electrodes, and the second with Zn and Ni electrodes, each in appropriate 1.00 M solutions of their ions. If connected as voltaic eels in series, which two metals are plated, and what is the total potential? If connected such that one cell acts as a battery to power the other as an electrolytic cell, which two metals are plated, and what is the total potential? If 3.00 g of metal is plated in the voltaic cell, how much metal is plated in the electrolytic cell?

Explanation / Answer

a) The two metals plated are,

Ag(s)

Ni(s)

total potential Eo = 2.963 V

b) When connected as battery, metals plated are,

Ag(s)

Zn(s)

Total potential = 1.947 V

c) If 3 g metal is placed in the voltaic cell, the amount of metal plated in th electrolytic cell would be,

= (3/107.8682) x 58.69 = 1.632 g