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Can someone please help me with this problems with details please? Use the react

ID: 1003782 • Letter: C

Question

Can someone please help me with this problems with details please? Use the reaction data in the table below to answer Questions 9-12 2c102 (aq) + 20H. (aq) CI03-(aq) + cio2-(aq) + H20 (1) Experiment Initial Rate Number (CIO21 (M) IOH ](M)(M/s) 0.060 0.020 0.020 0.030 0.0248 0.030 0.00276 0.090 0.00828 9) What is the order of the reaction with respect to Cl02? A) 4 B) 2 D) 1 10) What is the order of the reaction with respect to OH-? A) 1 B) 2 C) 3 D) 4 11) What is the overall order of the reaction? A) 4 B) 1 D) 2 12) What is the magnitude of the rate constant for the reaction? A) 230 B) 713 C) 4.6 D) 115 121 The halt, life of a firet-oction is 13 min If the initial concentration of reactant is 0.1

Explanation / Answer

Let the rate of reaction (r) = K[ ClO2] m [OH-]n, where m and n are orders of reactions with respect to m and n respectively. K is rate constant.

From experiment number 1

0.0248= K[0.060]m [0.030]n     (1), From experiment number 2

0.00276= K[0.020]m [0.030]n   (2), from experiment number 3

0.00828= K[ 0.020]m [0.090]n (3)

Eq.1/ Eq.2

0.0248/0.00276= (0.06/0.02)m,           m=2

With respect to ClO2, the order is 2. ( B is correct)

Eq.3/Eq.2 = 0.00828/0.00276=   (0.090/0.030)n

3= 3n , n=1

The order of the reaction with respect to [OH-] =1 ( A is correct)

Overall order of the reaction = 2+1=3 ( C is correct)

From Eq.1

0.0248= K[0.060]2 [0.030], K= 230 /M2.sec   ( A is correct)