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In the figure below, the change in internal energy of a gas that is taken from A

ID: 1377785 • Letter: I

Question

In the figure below, the change in internal energy of a gas that is taken from A to C along the blue path is +815 J. The work done on the gas along the red path ABC is -445 J.

(a) How much energy must be added to the system by heat as it goes from A through B to C?
J

(b) If the pressure at point A is five times that of point C, what is the work done on the system in going from C to D?
J

(c) What is the energy exchanged with the surroundings by heat as the gas goes from C to A along the green path?
J

(d) If the change in internal energy in going from point D to point A is +515 J, how much energy must be added to the system by heat as it goes from point C to point D?
J

Explanation / Answer

the change in internal energy of a gas that is taken from A to C along the blue path is U = +780 J
The work done on the gas along the red path ABC is W = -425 J.
(a)energy must be added to the system by heat as it goes from A through B to C is

    Q = U - W since from 1 st law of thermodynamics

        = 815 + 445 = 1260 J

(b) the pressure at point A is P ' = 5P

pressure at point C is P = P

the work done on the system in going from C to D is W ' = P * -dV

where   dV = change in volume

we know W = P ' * dV

from this  dV = W / P '

                     = -445 / 5P

                    = -89 / P

So, W ' = P * ( 89 / P ) = 89 J

(c) the energy exchanged with the surroundings by heat as the gas goes from C to A along the green path Q ' = W' - U     Since along the path change in internal enenrgy is +ve than in opposite direction it

                                           is -ve

             = - 89 J -815 J

             = - 904 J

(d) the change in internal energy in going from point D to point A is U ' = +515 J

energy must be added to the system by heat as it goes from point C to point D is

we know change in internal energy from C to D + change in internal enrgy from D to A = -U

               change in internal energy from C to D + U ' = -U

               change in internal energy from C to D = -U - U '

                                                                        = -815 -515 -89 J = - 1419 J