Bonus 1. Calculate the molar enthalpy of neutralization (delta H) in kj/mol of t
ID: 518540 • Letter: B
Question
Bonus 1. Calculate the molar enthalpy of neutralization (delta H) in kj/mol of the exothermal reaction between an aqueous acid and an aqueous base (assume 1:1 stoichiometry) given the following information: Temperature change = 6.23 degree C 50.0 mL of 2.0 M acid added to 50.0 mL of 2.0 M base Heat capacity of the calorimeter (C _= 6.50 J/degree C Specific heat for water = 4.184 J/E degree C You must show all of your work report your answer to the proper number of significant figures, and the appropriate sign.Explanation / Answer
dT = 6.23 °C
Total V = 50+50 = 100 mL
Asusme Density of solution = 1 g/mL
mass of solution = 100*1 = 100 g
mol of acid = MV = 50*2 = 100 mmol = 0.1 mol
Qsolution = m*C*dT
Qcalorimter = C*dT
Qtotal = Qsolution + Qcalorimter
Qtotal = Qreaction
Qtotal = 100*4.184*6.23 + 6.5*6.23 = 2647.127 J
so
Qreaction = -2647.127 J
then
HRxn = Qrxn/mol = -2647.127 / (0.1) = -26471.27 J/mol