MasteringChemistry. MCHW Ch14B Mozilla Firefox D a https://session.masteringchem
ID: 536939 • Letter: M
Question
MasteringChemistry. MCHW Ch14B Mozilla Firefox D a https://session.masteringchemistry.com/myct/itemview?assignmentProblemID 83532642 MCHW Ch14B Exercise 14.54 with feedback Exercise 14.54 with feedback Part A For the following reaction, KC 255 at 1000 K What is the equilibrium concentration of COat 1000 K? co (g) Cl2 (g) CoCl2 (g) Express your answer in molarity to three significant figures. A reaction mixture initially contains a CO concentration of 0.1470 M and a Cl2 concentration of 0.177 M at 1000 K You may want to reference (LD ages 667 677 section 14.8 while completing this problem. ICO) Submit My Answers Give U Incorrect: Try Again Part B What is the equilibrium concentration of Ch at 1000 K? Express your answer in molarity to three significant figures.Explanation / Answer
Kc = 255
Kc = [COCL2]/[CO][Cl2]
initially:
[CO] = 0.147
[Cl2] = 0.177
[COCl2] = 0
in equilibrium
[CO] = 0.147 - x
[Cl2] = 0.177 - x
[COCl2] = 0 + x
substitute in KC expression
Kc = [COCL2]/[CO][Cl2]
255 = x / (0.147-x)(0.177-x)
0.00392x = (0.147*0.177 - (0.147+0.177)x + x^2)
0.026019-0.32792x + x^2 = 0
x = 0.1345
now substitute in CO concentration
[CO] = 0.147 -0.1345 = 0.0125 M
[Cl2] = 0.177 - 0.1345 = 0.0425M
[COCl2] = 0 + 0.1345