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Mass of small beaker 112.64 g Mass of Fertilizer and Beaker 123.03 g Mass of fer

ID: 548444 • Letter: M

Question

Mass of small beaker

                       112.64 g

Mass of Fertilizer and Beaker

                        123.03 g

Mass of fertilizer sample

                         10.39 g  

Mass of filter paper

                            0.44 g     

Mass of filter paper and dry MgNH4PO4*6H2O precipitate

                            0.96 g

Mass of dry MgNH4PO4*6H2O precipitate

                             0.52 g

Moles of MgNH4PO4*6H2O

                          0.0021 mol

Moles of Phosphorous

                           0.0021 mol

Mass of Phosphorous

                            0.0065 g

% P in fertilizer sample

                                 .62 %                 

Moles of P2O5

                                  mol

Mass of P2O5

                                   g

% as P2O5 in fertilizer sample

                                    %

Mass of small beaker

                       112.64 g

Mass of Fertilizer and Beaker

                        123.03 g

Mass of fertilizer sample

                         10.39 g  

Mass of filter paper

                            0.44 g     

Mass of filter paper and dry MgNH4PO4*6H2O precipitate

                            0.96 g

Mass of dry MgNH4PO4*6H2O precipitate

                             0.52 g

Moles of MgNH4PO4*6H2O

                          0.0021 mol

Moles of Phosphorous

                           0.0021 mol

Mass of Phosphorous

                            0.0065 g

% P in fertilizer sample

                                 .62 %                 

Moles of P2O5

                                  mol

Mass of P2O5

                                   g

% as P2O5 in fertilizer sample

                                    %

Explanation / Answer

It is assumed that P2O5 is the source of P in the fertilizer. Assume a hypothetical decomposition of P2O5 (without charges on the ions).

P2O5 -------> 2 P + 5 O

As per the stoichiometric equation above,

1 mole P2O5 = 2 moles P.

We have deduced earlier that the fertilizer contained 0.0021 mole P; therefore, mole(s) of P2O5 = (0.0021 mole P)*(1 mole P2O5/2 mole P) = 0.00105 mole P2O5 (ans)

Molar mass of P2O5 = (2*30.9738 + 5*15.9994) g/mol = 141.9446 g/mol.

Mass of P2O5 in the fertilizer = (0.00105 mole)*(141.9446 g/mol) = 0.14904 g 0.149 g (ans).

% P2O5 in the fertilizer = (0.149 g)/(10.39 g)*100 = 1.434% (ans).