Please explain the answers thoroughlyas well as all the necessary steps arriving
ID: 686108 • Letter: P
Question
Please explain the answers thoroughlyas well as all the necessary steps arriving at the answers. Thanks.A buffer is prepared by mixing 525 mL of 0.50 M formic acid and 475mL of 0.50 M sodium formate. Given Ka= 1.7 X10-4. Calculate the pH using both the the equationfor the ionization showing all additives to the mixture and usingthe Henderson-Hasselbalch equation. Please explain the answers thoroughlyas well as all the necessary steps arriving at the answers. Thanks.
A buffer is prepared by mixing 525 mL of 0.50 M formic acid and 475mL of 0.50 M sodium formate. Given Ka= 1.7 X10-4. Calculate the pH using both the the equationfor the ionization showing all additives to the mixture and usingthe Henderson-Hasselbalch equation. Please explain the answers thoroughlyas well as all the necessary steps arriving at the answers. Thanks.
Explanation / Answer
According to Henderson-Hasselbalch equationpH = pKa + log ([salt ] / [acid]) pH = - log Ka +log ([salt ] / [ acid]) No. of moles of formic acid = Molarity * Volume in L = 0.5 * ( 0.525 + 0.475 ) = 0.5 mol No. of moles of sodium formate = 0.5 * (0.475 + 0.525 ) =0.5 mol Plug these values we have pH = - log Ka + log ( 0.5 / 0.5 ) = -log 1.7 X10-4 + 0 = 4 - log1.7 = 4 -0.2304 =3.7696 ~3.8