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AgCl(s) --------------------------> Ag^+ (aq) + Cl^- (aq) s s ksp = [Ag^+][Cl^-]

ID: 700201 • Letter: A

Question

AgCl(s) --------------------------> Ag^+ (aq) + Cl^- (aq)

                                                 s                  s

   ksp   = [Ag^+][Cl^-]

1.77*10^-10   = s*s

s^2              = 1.77*10^-10

   s               = 1.33*10^-5 M

the molar solubility of solution is 1.33*10^-5 M in water

b. NaCl(aq) ------------------> Na^+ (aq) + Cl^- (aq)

        0.08 M                                               0.08M

AgCl(s) --------------------------> Ag^+ (aq) + Cl^- (aq)

                                                 s                  s+0.08

   ksp   = [Ag^+][Cl^-]

1.77*10^-10   = s*(s+0.08)

1.77*10^-10    = s*0.08                       [0.08>>>s ,S+ 0.08 = 0.08]

s                    = 1.77*10^-10/0.08   = 2.2125*10^-9 M

The solubility of AgCl in NaCl is 2.2125*10^-9 M

Explanation / Answer

Calculate the molar solubility of AgCl (Ksp 1.77 x 10-10) in (a) pure water. (b) 0.08 M NaCl