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Substance -- Specific Heat (J / g-K) N2(g)--1.04 Al(s) --0.90 Fe(s)--0.45 Hg(l)/

ID: 790995 • Letter: S

Question

Substance --Specific Heat (J / g-K)


N2(g)--1.04


Al(s) --0.90


Fe(s)--0.45


Hg(l)/0.14


H2O(l)--4.18


CH4(g)--2.20


CO2(g)--0.84


CaCO3(s)--0.82


                    1. Which substance on the table requires smallest amount of energy to increase the temperature of 41.5 g of that substance by 11K?                


                    a) Express your answer as a chemical expression. Identify the phase in your answer.                


                    b) Calculate the energy needed for this temperature change.                


                    Express your answer in joules using 2 significant figures                


                    2. The metabolism of glucose yields CO2 (g) and water as products. Energy released in this metabolic process is converted to useful work,"w" with about 68%                    efficiency.                


                    Calculate the mass of glucose metabolized by a 81.1kg person climbing a mountain with an elevation gain of 1730 m. Assume that the work performed in the climb                    is four times that required to simply lift 81.1 kg by 1730 m.                


                    Delta H of Glucose -1273.3 kJ/mol

Explanation / Answer


1. (a) The answer is: Hg(l)

Hg(l) requires the least amount of energy since its specific heat is lowest


1. (b) Energy = mass x specific heat x temperature change

= 41.5 x 0.14 x 11

= 63.91 J = 64 J


2. Work = 4 x mass x standard gravity x height

= 4 x 81.1 x 9.807 x 1730

= 5503806 J = 5503.81 kJ


Moles of glucose (100% efficiency) = -work/Delta H

= 5503.81/1273.3 = 4.3225 mol


Moles of glucose (68% efficiency) = 100/68 x 4.3225

= 6.3566 mol


Mass of glucose = moles x molar mass of glucose

= 6.3566 x 180.16

= 1145 g = 1.145 kg (or approximately 1.15 kg)