Academic Integrity: tutoring, explanations, and feedback — we don’t complete graded work or submit on a student’s behalf.

Consider the voltaic cell below, which is symmetric except for the fact that [Cu

ID: 934076 • Letter: C

Question

Consider the voltaic cell below, which is symmetric except for the fact that [Cu2+] = 1.0 M on the left side and [Cu2+] = 0.01 M on the right. Both electrodes consist of a Cu electrode immersed in an aqueous Cu2+ solutioWhich electrode is positive, and what is Ecell?Cu/Cu2+, 1 M/Cu2+, 0.01 M/C

Left electrode is positive, and Ecell = 0.059 V
B) Right electrode is positive, and Ecell = 0.059 V
C) Left electrode is positive, and Ecell = 0.118 V
D) Right electrode is positive, and Ecell = 0.030 V
E) Right electrode is positive, and Ecell = 0.118 V

Explanation / Answer

Let us take the cell as given         Cu/Cu+2(1M)|| Cu+2(0.01M)/Cu

Lets write the cell reaction Cu   -----Cu+2(1M)    oxidation (negative)

                                                Cu+2(0.01M) ---Cu                            reduction (positive)

Cell reaction                       Cu+2(0.01M) ----- Cu+2(1M)        

Using Nernst equation

                Ecell          = Eo