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Fluoride, in the form of sodium silicofluoride (Na 2 SiF 6 ), is commonly added

ID: 955977 • Letter: F

Question

Fluoride, in the form of sodium silicofluoride (Na2SiF6), is commonly added to municipal drinking water to prevent tooth decay. It is generally added at a level of 1.0 mg/L, but its maximum concentration level (MCL) cannot exceed 4.0 mg/L. You have been assigned to prepare a liter of a standard solution that contains 1.000 mg/L fluoride.

Explain, in detail, how you would prepare this solution so a labmate could prepare it from your instructions. Your answer must include a brief explanation of the calculations you did to get the mass of substance that will be used to prepare the solution.

Fluoride, in the form of sodium silicofluoride (Na2SiF6), is commonly added to municipal drinking water to prevent tooth decay. It is generally added at a level of 1.0 mg/L, but its maximum concentration level (MCL) cannot exceed 4.0 mg/L. You have been assigned to prepare a liter of a standard solution that contains 1.000 mg/L fluoride.

Explanation / Answer

consider 1 L of solution

mass of fluoride = 1 mg = 1 x 10-3 g

now

we know that

moles= mass / molar mass

so

moles of fluoride = 1 x 10-3 / 19 = 5.263 x 10-5

now

consider Na2SiF6

we can see that

moles of Na2SiF6 = ( 1/6) x moles of fluoride

moles of Na2SiF6 = (1/6) x 5.263 x 10-5

moles of Na2SiF6 = 8.772 x 10-6

now

mass = moles x molar mass

so

mass of Na2SiF6 = 8.772 x 10-6 x 188

mass of Na2SiF6 = 1.65 x 10-3 g

mass of Na2SiF6 = 1.65 mg


so

the steps are

1) take 1.65 mg of Na2SiF6

2) add 1L of water

3) the solution contains 1 mg / L fluoride