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In a constant-pressure calorimeter, 1.60 g of NH4NO3 is mixed with 75.0 g of wat

ID: 958287 • Letter: I

Question

In a constant-pressure calorimeter, 1.60 g of NH4NO3 is mixed with 75.0 g of water at an initial temperature of 25.00 °C. After dissolution of the salt, the final temperature of the calorimeter contents is 23.34°C. Assuming the solution has a heat capacity of 4.18 J/°Cg and assuming no heat transfer between the calorimeter and its surroundings, calculate the enthalpy change for the dissolution of NH4NO3 in units of kJ/mol

(Answer:26.6 kJ/mol) (I know the answer, I just not sure how to use both of the grams when solving the equation, please write your steps so I can try a similar problem on my own. Thank you!)

Explanation / Answer

No of mol of NH4NO3 = 1.6/ 80.0434   = 0.02 mol

q absorbed = m*s*DT

          = (75+1.6)*4.18*(25-23.34)

          = 531.512 joule

          = 0.531 kj

DHrxn = 0.531/0.02 = 26.55 kj/mol