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If you were to replace 2-acetylpyridine with acetophenone in an adol reaction of

ID: 975664 • Letter: I

Question

If you were to replace 2-acetylpyridine with acetophenone in an adol reaction of 2-acetylpyridine and 4-nitrobenzaldehyde would the reaction speed increase, decrease, or stay the same? Why? How would you monitor this reaction to determine when it has reached completion? If you were to replace 2-acetylpyridine with acetophenone in an adol reaction of 2-acetylpyridine and 4-nitrobenzaldehyde would the reaction speed increase, decrease, or stay the same? Why? How would you monitor this reaction to determine when it has reached completion?

Explanation / Answer

The rate of aldol condensatio will increase .

The reason is acetophenone is more acidic than 2-acetylpyridine so the acidic hydrogen is removed more rapidly.