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Part C - The Synthesis and Analysis of an Iron Oxalato Transition Metal Complex

ID: 1033121 • Letter: P

Question

Part C - The Synthesis and Analysis of an Iron Oxalato Transition Metal Complex Lab Report

You have entered the following experimental values:

Molarity of your standardized KMnO4 solution : 0.0153 M

.

Balance the equation below for the reaction between MnO4? and C2O42?.

2MnO4? + 16H+ + 5C2O42? ? 2Mn2+ + 10CO2 + 8H2O

Calculate the corrected volumes for KMnO4:

Calculate the moles of KMnO4 added :

Calculate the moles of C2O42? in the sample :

Calculate the mass of C2O42? in the sample :

Calculate the percent of C2O42? in the sample :


Now, using the statistical treatment of data, calculate the percent of C2O42? in your sample
:

Experiment Number #1 #2 #3 #4 Mass of sample (g) 0.127 0.128 0.122 0.120 Volume of KMnO4 required (mL) : 20.80 24.50 25.50 22.00 Volume of blank titration (mL) : 0.0500 0.0500 0.0500 0.0500

Explanation / Answer

For the given experiment,

Expt No.                                        #1         #2         #3       #4

KMnO4 corrected volume (ml)     20.75    20.45    25.45   21.95

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moles of KMnO4 added = molarity of KMnO4 x volume of KMnO4 added

molarity of KMnO4 = 0.0153 M

Expt No.                                              #1         #2            #3          #4

moles of KMnO4 added (mmol)        0.32      0.313       0.390     0.336

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moles C2O4^2- present in sample = moles KMnO4 x 5/2

Expt No.                                              #1         #2            #3          #4

moles of KMnO4 added (mmol)        0.80      0.782       0.975     0.840

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mass C2O4^2- in sample = moles C2O4^2- x 88.02 g/mol

Expt No.                                              #1         #2            #3          #4

moles of KMnO4 added (mg)            70.42     68.83      85.82     73.94

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Percent C2O4^2- in sample = mass C2O4^2- in sample x 100/mass of sample

Expt No.                                              #1         #2            #3          #4

moles of KMnO4 added (mg)            55.45     53.77      70.34      61.62

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Average percent C2O4^2- in sample = 60.30%