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Consider the following reaction and identify the reagent required for the reacti

ID: 1063965 • Letter: C

Question

Consider the following reaction and identify the reagent required for the reaction Pd/CaCO_3 KMnO_4/Ethanol BH3/THF H_2SO_4 none of these Identify the alkyne that cannot make an acetylide anion in the presence of Sodium amide. 3-Octyne 2-Hexyne 2-Decene 2-pentyne All of them Identify the correct IUPAC name of the following structure Cl-CH_2-CH_2-CH identicalto CH-CH_2-CH_2-CH_2-Br l-Chloro-7-bromo-2-heptene 7-Bromo-l-chloro-2-heptene 7-Bromo-l-chloro-3-heptene 1-Bromo-7-chloro-4-heptene Identify the halide that most reactive to go SN^2 substitution I II I and II I, II, and III All of them Elimination reaction of 3-Bromo2. 2-Methyl-2-pentene 2-Methyl-3-pentene 3-Methyl-2-pentene None of them All of them

Explanation / Answer

6. option E

A triple bond is oxidised to carboxylic acid with strong oxidising agents like KMNo4 in acidic medium. not in alcoholic medium.

7.option E

ONly 1- alkynes form alkynide ions with sodamide. So none can form alkynide in the gven examples

8. option C

At the first point of difference doible bond occurs at 3 carbon. Thus the name is 7-bromo-1-chloro -3-heptene

9.For Sn2 steric factor pplays an important role. Methyl bromide is the one with least steric hindrance for the backside nuclophilic attack in SN2.

Thus option A.

10. Option A

Elimination of 3-bromo2-methyl pentane predominantly gives the Saytzef product, tht is the more substituted alkene. Here it is 2-methyl-2-pentene.