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Please Explain the pre-lab questions The reaction by which the red tetrazolium t

ID: 54029 • Letter: P

Question

Please Explain the pre-lab questions

The reaction by which the red tetrazolium test gives a positive result. The product is insoluble and red in color. A table of this nature should be in your lab notebook. Make the squares large enough to record visual observations. Which reagent would be best for converting D-fructose to D-mannitol? What determines whether or not a sugar is reducing? Draw a mechanism for the reaction in Figure 2. Before coming to lab; fill out Table 1 with expected results. Draw a '+' where you expect a positive test result and a where you expect a negative or no result. If you don't fill this out correctly before lab, you won't be able to do the lab and will be given a zero.

Explanation / Answer

1. NaBH4 reduces D-fructose to a mixture of alditols (aldo alcohols) D-glucitol and D-mannitol at 1:1 ratio.

2. A sugar will be a reducing sugar if it has an open chain conformation, with a free aldehyde/keto group or a free hemiaetal/hemiketal group.

4.

Molisch’s test

Red – tetrazolium

Barfoed’s

Bial’s test

Seliwanov’s Test

D-Fructose

+

+

+

+

+

D-glucose

+

+

+

+

+

Lactose

+

+

+

-

-

D-Mannitol

+

+

+

-

-

Sucrose

+

-

-

-

-

D-Xylose

+

+

+

+

+

Molisch’s test

Red – tetrazolium

Barfoed’s

Bial’s test

Seliwanov’s Test

D-Fructose

+

+

+

+

+

D-glucose

+

+

+

+

+

Lactose

+

+

+

-

-

D-Mannitol

+

+

+

-

-

Sucrose

+

-

-

-

-

D-Xylose

+

+

+

+

+