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In a coffee-cup calorimeter, 1 mol NaOH and 1 mol HCl initially at 18.5 o C (Cel

ID: 970719 • Letter: I

Question

In a coffee-cup calorimeter, 1 mol NaOH and 1 mol HCl initially at 18.5 oC (Celsius) are mixed in 100g of water to yield the following reaction:

NaOH + HCl Na+(aq) + Cl-(aq) + H2O(l)


After mixing the temperature rises to 107 oC. Calculate the change in enthalpy of this reaction.

Specific heat of the solution = 4.184 J/(g oC)

State your answer in kJ with 3 significant figures. Don't forget to enter the unit behind the numerical answer.

The molecular weight of NaOH is 40.0 g/mol, and the molecular weight of HCl is 36.5 g/mol.

H =

Explanation / Answer

NaOH + HCl Na+(aq) + Cl-(aq) + H2O(l)


mass of solution = 100+40+36.5 = 176.5 grams

heat released = m*s*DT

    = 176.5*4.18*(107-18.5)

     = 65.3 kj

enthalpy of reaction = - 65.3 kj/mol