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The following H NMR spectrum and 13C NMR spectrum is the spectrum of trans-4-t-b

ID: 998495 • Letter: T

Question

The following H NMR spectrum and 13C NMR spectrum is the spectrum of trans-4-t-butylcyclohexanol. Fill in the table below. (When writing assignment in the table, please indicate as for example -CH3, -OH, etc, not HA, HB, etc).

1H NMR (400 MHz, CDCl3)

13C NMR (100 MHz, CDCl3)

Chemical shifts (ppm)

No. of hydrogens

Multiplicity

Assignment

Chemical shifts (ppm)

Assignment

1H NMR (400 MHz, CDCl3)

13C NMR (100 MHz, CDCl3)

Chemical shifts (ppm)

No. of hydrogens

Multiplicity

Assignment

Chemical shifts (ppm)

Assignment

Explanation / Answer

Chemical shift (ppm) No. of hydrogens multiplicity assignment     Chemical shifts (ppm)        assignment

0.83                                  9H                     singlet              C(CH3)3         27.6                             (CH3)3

0.91-1.01                       3H (2+1)               multiplet          CH2 and CH     25.9 and 47.1               CH2 and CH

1.15-1.24                       2H                         multiplet            CH2                    25.9                             CH2

1.74-1.78                       2H                       multiplet               CH2                   36.0                            CH2

1.81                              1H                         singlet                OH                     71.1                           CH-OH

1.96-2.01                       2H                          multiplet            CH2                    36.0                            CH2