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Toous VIEW Stereochemistry Workshop Spring 20 7 (Protected View) Word PROTECTED

ID: 504686 • Letter: T

Question

Toous VIEW Stereochemistry Workshop Spring 20 7 (Protected View) Word PROTECTED VIEW Be careful files from the Internet can contain viruses. Unless you need to ed its safer to stay in Protected View. Enable Editing Workshop Problems CHMI 303 Spring 2017 Br and 1. Assign (R) or (S) as appropriate to each of the following CH CHO and H,CH2' H3CH2 H CH H B Hac H H, CH3 H Br HJCH2C CH HO CN H- CH2CH3. and CH2CH3 HN 3. ldentify the relat onship between each ofthe follow ng pairs of structures (Say whether CH3 H20H HO. they represent the same compound emantuomers or dastereomers) CH2CH3 COO COOH COOH COOH HOY and and CH2CH2 COOH COOH H1CT COOH HPH CH3 CH HO H H CH H OH H C 4. Using the templates below draw Fisher projections for all the structures in Question-3 2. Identify the relationship between each of the following pairs of structures. (Say whether and and they represent the same campound, enantiamers or diastereamers) CH, CH2CH3 and H3CH2C CH2CH3 5. Which of the following is (S)-2-bromobutane? SCREENS 009 AM 27/2017

Explanation / Answer

Ans 1 An R conformer has clockwise arrangement of substituents from high priority to low priority

Whereas the S has it anticlockwise

Since we can do just 4 subparts, let me help you out with first four!

1st structure is S , as you can see it is anticlockwise from alcoholic group to bromide

Second is R, clockwise, from OH to Br

Third is R, clockwise from Br to ethyl group

Fourth is S, anticlockwise from Br to ethyl .