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Strong base is dissolved in 565 mL of 0.400 M weak acid (Ka 4.20 x105) to make a

ID: 696218 • Letter: S

Question

Strong base is dissolved in 565 mL of 0.400 M weak acid (Ka 4.20 x105) to make a buffer with a pH of 4.19 Assume that the volume remains constant when the base is added. HA(aq)-OH-(aq) H2O(l)+ A-(aq) Calculate the pKa value of the acid and determine the number of moles of acid initially present. Number Number pk. 114.38 0.226 mol HA When the reaction is complete, what is the concentration ratio of conjugate base to acid? Number = 110.646 HA How many moles of strong base were initially added? Incorrect. Look in the bottom panel for more specific feedback Number 0.105 mol OHhow to do this part of the calculation

Explanation / Answer

if ratio is

A-/HA = 0.646

and

HA initially = MV = 0.4*0.565 = 0.226

then

A- = 0.646HA

and we know

A- + HA = 0.226

substitute

0.646HA + HA = 0.226

HA = 0.226/(1+0.646)

HA = 0.13730

therefore,

A- = 0.646HA =0.646* 0.13730 = 0.0886958 mol of OH- was added