Consider the reaction: Glucose 6 phosphate <==> Fructose 6-phosphate Q 1: If the
ID: 887145 • Letter: C
Question
Consider the reaction:
Glucose 6 phosphate <==> Fructose 6-phosphate
Q 1: If the Keq for this reaction is 0.5 what does it imply about it?
A) Under standard conditions, the formation of fructose 6-phosphate is favored
B) Under standard conditions, the formation of glucose 6-phosphate is favored
C) Under standard conditions equal amounts of both gluose 6-phosphate and fructose 6-phosphate will be made
Q2:
What will the standard free energy change be for this reactions? Assume temp = 25C (show work)
Explanation / Answer
Q 1 ) Answer : B) Under standard conditions, the formation of glucose 6-phosphate is favored
explanation : Keq < 1 --------------> reaction favoured to backward direction
Keq > 1 --------------> reaction favoured to forward direction
Keq = 1 -------------------> at equilibrium
here Keq = 0.5 means reaction favoured to backward direction
Q2)
R = 8.314 x 10^-3 kJ / mol -K
T = 25 + 273 = 298 K
delta Go = - RT ln Keq
= - 2.303 R T log Keq
= - 2.303 x 8.314 x 10^-3 x 298 x log (0.5)
= 1.72 kJ /mol
delta Go = 1.72 kJ / mol