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Part A Determine the enthalpy for this reaction: Ca(OH)2(s)+CO2(g)CaCO3(s)+H2O(l

ID: 909264 • Letter: P

Question

Part A

Determine the enthalpy for this reaction:

Ca(OH)2(s)+CO2(g)CaCO3(s)+H2O(l)

Express your answer in kilojoules per mole to one decimal place.

Part B

Consider the reaction

Ca(OH)2(s)CaO(s)+H2O(l)

with enthalpy of reaction

Hrxn=65.2kJ/mol

What is the enthalpy of formation of CaO(s)?

Express your answer in kilojoules per mole to one decimal place.

± Enthalpy

Enthalpy H is a measure of the energy content of a system at constant pressure. Chemical reactions involve changes in enthalpy, H, which can be measured and calculated:

Hrxn=productsmHfreactantsnHf

where the subscript "rxn" is for "enthalpy of reaction" and "f" is for "enthalpy of formation" and m and nrepresent the appropriate stoichiometric coefficients for each substance.

The following table lists some enthalpy of formation values for selected substances.

Hrxn= kJ/mol

Explanation / Answer

Ca(OH)2(s)+CO2(g)CaCO3(s)+H2O(l)

Check if bbalanced:

it is balanced

H = Hprod - Hreact = (1207.0 + 285.8)-(986.1+-393.5) = -113.2 kJ/mol

B)

when

Ca(OH)2(s)CaO(s)+H2O(l) Hrxn=65.2kJ/mol

then

Hrxn = Hprod - Hreact

65.2 = HCaO + HH2O - HCa(OH)2

65.2 = HCaO + 285.8 - 986.1 = 700.3

65.2 = HCaO + 700.3

HCaO = 65.2-700 = -634.8