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Please help A.)A 1.0-L buffer solution contains 0.100 mol HC2H3O2 and 0.100 mol

ID: 965346 • Letter: P

Question

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A.)A 1.0-L buffer solution contains 0.100 mol HC2H3O2 and 0.100 mol NaC2H3O2. The value of Ka for HC2H3O2 is 1.8×105.

Calculate the pH of the solution, upon addition of 0.085 mol of NaOH to the original buffer.

B.Calculate the

pH of the buffer that results from mixing 51.0 mL of a 0.488 M solution of HCHO2 and 16.0 mL of a 0.571 M solution of NaCHO2. The Kavalue for HCHO2 is 1.8×104.

C.Consider a buffer solution that is 0.50

M in NH3and 0.20 M in NH4Cl. For ammonia, pKb=4.75.

Calculate the pH of 1.0 L of the solution, upon addition of 49.00 mL of 1.0 MHCl.

D.)A 1.0-

L buffer solution contains 0.100 molHC2H3O2 and 0.100 molNaC2H3O2. The value of Ka for HC2H3O2 is 1.8×105.

Calculate the pH of the solution upon addition of 19.1 mL of 1.00 MHCl to the original buffer.

Explanation / Answer

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A.)A 1.0-L buffer solution contains 0.100 mol HC2H3O2 and 0.100 mol NaC2H3O2. The value of Ka for HC2H3O2 is 1.8×105.

Calculate the pH of the solution, upon addition of 0.085 mol of NaOH to the original buffer.   

this is a buffer so

pH = pKa + log(A-/HA)

After adding base, we change acid to conjugate so:

mmol of HA = 0.1 - 0.085 = 0.015

mmol of A- = 0.1 + 0.085 =0.185

pH = 4.75 + log(0.185/0.015) = 5.84

pH of buffer after addition = 5.84

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