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Particle in a box energy formula: En = n 2 h 2 /8mL 2 The particle-in-a-box ener

ID: 864161 • Letter: P

Question

Particle in a box energy formula: En = n2h2/8mL2

The particle-in-a-box energy formula may be used to predict the wavelengths of photons required to optically excite such as quantum system.

(a) obtain an expression for the wavelength of a photon required to induce a particle-in-a-box to undergo a transition from an inital state with quantum number ni to a final state with quantum number nf, expressed as a function of the particle mass m and the length of the box L (as well as other constants)

(b) use the above result to predict thre wavelength (in nm) of a photon that would be required to promote an electron from a state with ni = 5 to nf = 6, if it is confined within a one-dimentional box of 1nm length.

Explanation / Answer

http://tinypic.com/r/av4z9f/8